Open Access Repository
Synthesis of Symmetrical Poly(pyridin-2-y1)ethane Ligands
Altmetric
Download Statistics
Downloads
Downloads per month over past year
Canty, AJ and Minchin, NJ 1986
, 'Synthesis of Symmetrical Poly(pyridin-2-y1)ethane Ligands'
, Australian Journal of Chemistry, vol. 39, no. 7
, pp. 1063-1069
, doi: 10.1071/CH9861063.
![]() |
PDF
AJC1986_2C_1063...pdf | Request a copy Full text restricted Available under University of Tasmania Standard License. |
Official URL: http://www.publish.csiro.au/nid/51/paper/CH9861063...
Abstract
Reaction of lithium derivatives of pyridin-2-ylmethanes, (C5H4N)CRR'- Li+, with mercury(II) iodide results in precipitation of mercury, and formation of symmetrical poly(pyridin-2-y1)ethanes [(C5H4N)CRR']2 (R = H, R' = Ph; R = Me, R' = Ph; R = R' = Me; R = C5H4N, R' = H; R = C5H4N, R' = Me). For [(C5H4N)CRPh]2 (R = H, Me) mixtures of the meso
and racemic diastereoisomers were found. Two of the products, [(C5H4N)CHPh]2 and [(C5H4N)2CH]2, were obtained in high yield, and readily form palladium(II) acetate complexes, Pd(02CMe){(rac-[(C5H4N)CHPh]2} and [Pd(02CMe)2][(C5H4N)2CH]2. The synthesis of 2-(1-phenylethy1)pyridine and a convenient route to bis(pyridin-2-y1)methane are described.
Item Type: | Article |
---|---|
Authors/Creators: | Canty, AJ and Minchin, NJ |
Journal or Publication Title: | Australian Journal of Chemistry |
ISSN: | 0004-9425 |
DOI / ID Number: | 10.1071/CH9861063 |
Item Statistics: | View statistics for this item |
Actions (login required)
![]() |
Item Control Page |