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The Structure of [PdC12{(Py)2(PyH)CH-N',N"}][PdCl4]0.5.2H20 (Py = Pyridin-2-yl),a Complex with Protonated 2,2',2"-Methylidynetrispyridine as a Bidentate Ligand

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Canty, AJ, Minchin, NJ, Skelton, BW and White, AH 1992 , 'The Structure of [PdC12{(Py)2(PyH)CH-N',N"}][PdCl4]0.5.2H20 (Py = Pyridin-2-yl),a Complex with Protonated 2,2',2"-Methylidynetrispyridine as a Bidentate Ligand' , Australian Journal of Chemistry, vol. 45, no. 2 , pp. 423-427 , doi: https://doi.org/10.1071/CH9920423.

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Abstract

Crystals of dichloro[2,2',2"-methylidynetris(pyridin)-1- ium- N',N"]palladium(II) hemi[tetrachloropalladate(II)] dihydrate are monoclinic, P21/c, a 8.558(5), b 15.516(7), c 16.153(5) a, beta 112.07(4), Z 4. The cations [PdCl2 {(Py)2(PyH)CH-N',N")]+ have square-planar geometry
for palladium, with the ligand in a boat conformation and having an uncoordinated protonated pyridine group. The complex contains monoprotonated tris(pyridin-2-yl)methane as a bidentate ligand.

Item Type: Article
Authors/Creators:Canty, AJ and Minchin, NJ and Skelton, BW and White, AH
Journal or Publication Title: Australian Journal of Chemistry
ISSN: 0004-9425
DOI / ID Number: https://doi.org/10.1071/CH9920423
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