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Structural Chemistry of the Platinum Group Metals: the Palladacyclopentane Complex (Butane-1,4-diyl)(N,N,N',N'-tetramethyl-ethylenediamine)palladium(II)

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Canty, AJ, Skelton, BW, Traill, PR and White, AH 1994 , 'Structural Chemistry of the Platinum Group Metals: the Palladacyclopentane Complex (Butane-1,4-diyl)(N,N,N',N'-tetramethyl-ethylenediamine)palladium(II)' , Australian Journal of Chemistry, vol. 47, no. 11 , pp. 2119-2122 , doi: 10.1071/CH9942119.

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Abstract

A single-crystal X-ray structure determination of the reagent (butane-1.4-diyl)(N,N,N',N'-
tetramethylethylenediamine)palladium(II) has shown that crystals are orthorhombic, Pbca, a 15.832(3), b 14.128(9),
c 11.451(3) A, Z 8. The square planar complex has a puckered PdCH2CH2CH2CH2 palladacyclopentane ring and a puckered PdNMe2CH2CH2NMe2 ring in which the outer carbon atoms deviate by ca. +/- 0.35 A from the 'PdC2N2' mean plane.

Item Type: Article
Authors/Creators:Canty, AJ and Skelton, BW and Traill, PR and White, AH
Journal or Publication Title: Australian Journal of Chemistry
ISSN: 0004-9425
DOI / ID Number: 10.1071/CH9942119
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