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High Co-ordination Numbers for Methylmercury(II); X-Ray and 1H N.M.R. Studies of [MeHgL]NO3 (L = 4,4’,4”-Triethyl-2,2’:6’,2”-terpyridyl and Di-2-pyridylmethane)

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Canty, AJ and Hayhurst, G and Chaichit, N and Gatehouse, BM (1980) High Co-ordination Numbers for Methylmercury(II); X-Ray and 1H N.M.R. Studies of [MeHgL]NO3 (L = 4,4’,4”-Triethyl-2,2’:6’,2”-terpyridyl and Di-2-pyridylmethane). Journal of the Chemical Society, Chemical Communications, 7. pp. 316-318. ISSN 1477-9226

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Abstract

Methylmercury(II) forms complexes [MeHgL]NO3 (L = 2,2’: 6’,2”-terpyridyls and di-2-pyridylmethane) where the ligands L are bidentate in methanol, but tridentate and bidentate, respectively, in the solid state with co-ordination geometries for mercury based on a
near linear dominant C-Hg-N unit with additional weak
Hg-N bonding.

Item Type: Article
Journal or Publication Title: Journal of the Chemical Society, Chemical Communications
Page Range: pp. 316-318
ISSN: 1477-9226
Identification Number - DOI: 10.1039/C39800000316
Date Deposited: 05 Feb 2008 22:27
Last Modified: 18 Nov 2014 03:27
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