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Dimethylmetal(III) Pyrazolides


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Byers, PK, Canty, AJ, Mills, K and Titcombe, LA 1985 , 'Dimethylmetal(III) Pyrazolides' , Journal of Organometallic Chemistry, vol. 295, no. 3 , pp. 401-405 , doi: 10.1016/0022-328X(85)80325-9.

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The complexes Me2Au(R2pz) (R = H, Me; pzH = pyrazole) are formed on reaction of dimethylgold(III) nitrate with 3,5-disubstituted pyrazoles, R2pzH, in water, but a similar procedure with Ph2pzH followed by recrystallization from
CHCl3/CCl4 gives [Me2Au(Ph2pzH)2] The complexes Me2M(Ph2pz) (M = Au, Tl), Me2In(Ph2pz). 1/2CH2Cl2, and Me2Tl(Me2pz) are formed on reaction of Me2MI (M = Au, Tl) or Me2InCl with Ag(R2pz) in nonaqueous
solvents. The complexes Me2Au(R2pz) (R = H, Me, Ph) are dimeric in chloroform and Me2Tl(Me2pz) is dimeric in benzene, but osmometric data for Me2Tl(Ph2pz) in benzene indicate presence of a monomer-dimer equilibrium.

Item Type: Article
Authors/Creators:Byers, PK and Canty, AJ and Mills, K and Titcombe, LA
Journal or Publication Title: Journal of Organometallic Chemistry
ISSN: 0022-328X
DOI / ID Number: 10.1016/0022-328X(85)80325-9
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