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Unsymmetric Tripod Ligands Related To Tris(pyrazol-1-yl)methane

Byers, PK, Canty, AJ, Honeyman, RT, Gardinier, JR and Reger, DL 2004 , 'Unsymmetric Tripod Ligands Related To Tris(pyrazol-1-yl)methane' , Inorganic Syntheses, vol. 34 , pp. 30-34 .

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Abstract

The syntheses of tripodal ligands related to tris(pyrazol-1-yl)methane are described. The synthesis of bis(pyrazol-1-yl)methanone, N-methylimidazole-2-carbaldehyde, bis(pyrazol-1-yl)(pyridin-2-yl)methane and bis(pyrazol-1-yl)(N-methylimidazol-2-yl)methane are documented. The synthetic strategy relies on condensation of bis(pyrazol-1-yl)methanone, (pz)2C=O, with aldehydes, R(H)C=O, to give (pz)2(R)CH and carbon dioxide.

Item Type: Article
Authors/Creators:Byers, PK and Canty, AJ and Honeyman, RT and Gardinier, JR and Reger, DL
Journal or Publication Title: Inorganic Syntheses
ISSN: 0073-8077
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