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Organometallic Chemistry of Palladium and Platinum with Poly(pyrazol-1-yl)alkanes and Poly(pyrazol-1-yl)borates

journal contribution
posted on 2023-05-26, 11:05 authored by Byers, PK, Canty, AJ, Honeyman, RT
The poly(pyrazol-1-yl)alkane ligands have been important in the development of the organometallic chemistry of palladium and platinum, and recent new applications have included their role in stabilising organopalladium(IV) compounds and in the synthesis of intramolecular coordination systems containing tripodal [N~C~N]- ligands coordinated to platinum(IV). This review includes these two new areas of poly(pyrazol-1-yl)alkane chemistry, and includes comparisons with earlier organopalladium and organoplatinum chemistry, and related chemistry where appropriate. In addition to poly(pyrazol-1-yl)alkanes and poly(pyrazol-1-yl)borates, closely related polydentate ligands contining at least one pyrazol-1-yl (pz) group are included, in particular, ligands containing the pyridin-2-yl (py) and N-methylimidazol-2-yl (mim) groups.

History

Publication title

Advances in Organometallic Chemistry

Volume

34

Pagination

1-65

ISSN

0065-3055

Publication status

  • Published

Rights statement

The definitive version is available at http://www.sciencedirect.com

Repository Status

  • Restricted

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