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Abstract

A synthesis of unconjugated (E)‐enediynes from allenyl amino alcohols is reported and their gold‐catalyzed cascade cycloaromatization to a broad range of enantioenriched substituted isoindolinones has been developed. Experimental and computational studies support the reaction proceeding via a dual‐gold σ,π‐activation mode, involving a key gold‐vinylidene‐ and allenyl‐gold‐containing intermediate.

Item Type:	Article
Authors/Creators:	Zamani, F and Babaahmadi, R and Yates, BF and Gardiner, MG and Ariafard, A and Pyne, SG and Hyland, CJT
Keywords:	density functional theory, activation energy, dual gold-catalysis, unconjugated (E)-enediynes
Journal or Publication Title:	Angewandte Chemie
Publisher:	Wiley
ISSN:	0044-8249
DOI / ID Number:	10.1002/anie.201810794
Copyright Information:	Copyright 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
Related URLs:	Google Scholar: Yates, BF UTAS Profile: Yates, BF UTAS Profile: Gardiner, MG Google Scholar: Ariafard, A UTAS Profile: Ariafard, A
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