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Abstract

We have investigated the capacity of a range of structurally-diverse, photoactive rhenium(I) tricarbonyl complexes featuring either tetrazolato or N-heterocyclic carbene (NHC) ligands to facilitate fundamental classes of visible-light-mediated photoredox-catalysed reactions. In this study, we demonstrate that these systems mediate representative atom-transfer radical addition, hydrodehalogenation, and α-amino C–H functionalisation reactions. These rhenium(I) complexes provide greater or at least comparable reactivity to the prototypical photoredox catalyst [Ru(bpy)3]2+ in many cases.

Item Type:	Article
Authors/Creators:	Nicholls, TP and Burt, LK and Simpson, PV and Massi, M and Bissember, AC
Keywords:	rhenium, photoredox catalysis
Journal or Publication Title:	Dalton Transactions
Publisher:	Royal Soc Chemistry
ISSN:	1477-9226
DOI / ID Number:	https://doi.org/10.1039/C9DT02533B
Copyright Information:	© The Royal Society of Chemistry 2019
Related URLs:	UTAS Profile: Bissember, AC
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