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Aryl–Fluoride Bond-Forming Reductive Elimination from Nickel(IV) Centers
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Meucci, EA, Ariafard, A 
ORCID: 0000-0003-2383-6380, Canty, AJ, Kampf, JW and Sanford, MS 2019
, 'Aryl–Fluoride Bond-Forming Reductive Elimination from Nickel(IV) Centers'
, Journal of the American Chemical Society, vol. 141, no. 33
, pp. 13261-13267
, doi: https://doi.org/10.1021/jacs.9b06896.
ORCID: 0000-0003-2383-6380, Canty, AJ, Kampf, JW and Sanford, MS 2019
, 'Aryl–Fluoride Bond-Forming Reductive Elimination from Nickel(IV) Centers'
, Journal of the American Chemical Society, vol. 141, no. 33
, pp. 13261-13267
, doi: https://doi.org/10.1021/jacs.9b06896.
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Abstract
The treatment of pyridine- and pyrazole-ligated NiII σ-aryl complexes with Selectfluor results in C(sp2)–F bond formation under mild conditions. With appropriate design of supporting ligands, diamagnetic NiIV σ-aryl fluoride intermediates can be detected spectroscopically and/or isolated during these transformations. These studies demonstrate for the first time that NiIV σ-aryl fluoride complexes participate in challenging C(sp2)–F bond-forming reductive elimination to yield aryl fluoride products.
| Item Type: | Article |
|---|---|
| Authors/Creators: | Meucci, EA and Ariafard, A and Canty, AJ and Kampf, JW and Sanford, MS |
| Keywords: | nickel catalysis, aryl-F bond formation |
| Journal or Publication Title: | Journal of the American Chemical Society |
| Publisher: | American Chemical Society |
| ISSN: | 0002-7863 |
| DOI / ID Number: | https://doi.org/10.1021/jacs.9b06896 |
| Copyright Information: | Copyright © 2019 American Chemical Society |
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| Item Statistics: | View statistics for this item |
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