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Crystal and Molecular Structure of (3,3'-Dimethyl-2,2'-bipyridyl)methylmercury(II) Nitrate; a Complex That May Have Weak Intramolecular pi-Coordination
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Canty, AJ, Chaichit, N, Gatehouse, BM and Marker, A 1978
, 'Crystal and Molecular Structure of (3,3'-Dimethyl-2,2'-bipyridyl)methylmercury(II) Nitrate; a Complex That May Have Weak Intramolecular pi-Coordination'
, Acta Crystallographica Section B-Structural, vol. B34, no. 11
, pp. 3229-3233
, doi: 10.1107/S0567740878010559.
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AC_1978,_3229.pdf | Request a copy Full text restricted Available under University of Tasmania Standard License. |
Official URL: http://dx.doi.org/10.1107/S0567740878010559
Abstract
The structure of the methylmercury complex of 3,3'-dimethyl-2,2'-bipyridyl(L), [MeHg(L)]NO3, was solved by Patterson and Fourier techniques using 1560 counter-measured observed reflections and refined by the full-matrix least-squares method to R = 0·061. The complex has a bent C(1)-Hg-N(1) group [172·7(5)] with Hg-C(1) 2·01(1) and Hg-N(1) 2·11(1) A, weak interaction between mercury and nitrate oxygen atoms, and evidence suggesting the presence of a weak intramolecular-interaction between mercury and the second pyridyl ring, with Hg-C(2') 3·11(1), Hg-N(l') 3·29(1) A and an angle of 100·5 between the planes of the pyridyl rings.
Item Type: | Article |
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Authors/Creators: | Canty, AJ and Chaichit, N and Gatehouse, BM and Marker, A |
Journal or Publication Title: | Acta Crystallographica Section B-Structural |
ISSN: | 0108-7681 |
DOI / ID Number: | 10.1107/S0567740878010559 |
Additional Information: | The definitive version is available at www.blackwell-synergy.com |
Item Statistics: | View statistics for this item |
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