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Identification of the side products that diminish the yields of the monoamidated product in metal-catalyzed C−H amidation of 2‑phenylpyridine with arylisocyanates
McKay, AI, Altalhi, WAO, McInnes, LE, Czyz, ML, Canty, AJ, Donnelly, PS and O'Hair, RAJ 2020
, 'Identification of the side products that diminish the yields of the monoamidated product in metal-catalyzed C−H amidation of 2‑phenylpyridine with arylisocyanates'
, The Journal of Organic Chemistry, vol. 85
, 2680−2687
.
Full text not available from this repository.
Abstract
The Ru(II)-catalyzed amidation of 2-arylpyridines with aryl isocyanates via C–H bond activation is less efficient than described previously, due to the formation of a series of side products, which were readily identified using direct infusion electrospray mass spectrometry and high-performance liquid chromatography–mass spectrometry.
| Item Type: | Article |
|---|---|
| Authors/Creators: | McKay, AI and Altalhi, WAO and McInnes, LE and Czyz, ML and Canty, AJ and Donnelly, PS and O'Hair, RAJ |
| Keywords: | catalysis, ruthenium catalysis, organic synthesis, amidation, DFT, mass spectrometry |
| Journal or Publication Title: | The Journal of Organic Chemistry |
| Publisher: | Amer Chemical Soc |
| ISSN: | 0022-3263 |
| Copyright Information: | © 2020 American Chemical Society |
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| Item Statistics: | View statistics for this item |
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