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Dimethylpalladium(II) and Monomethylpalladium(II) Reagents and Complexes


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Byers, PK, Canty, AJ, Jin, H, Kruis, D, Markies, BA, Boersma, J, van Koten, G, Hill, GS, Irwin, MJ, Rendina, LM and Puddephatt, RJ 1998 , 'Dimethylpalladium(II) and Monomethylpalladium(II) Reagents and Complexes' , Inorganic Syntheses, vol. 32 , pp. 162-172 .

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Syntheses of organopalladium(II) reagents containing N,N,N',N'-tetramethylethylenediamine (tmeda), pyridazine, dimethylsulfide, 2,2'-bipyridine (bpy), triphenylphosphine and bis(1,1'-diphenylphosphino)ferrocene (dppf) are described, together with trans-dichlorobis(dimethylsulfide)palladium(II) and trans-dibromobis(dimethylsulfide)palladium(II). Syntheses are described for dimethyl(pyridazine)palladium(II), monomethylpalladium(II) complexes of dimethylsulfide, [PdMe(SMe2)(mu-X)]2 (X = Cl, Br, I), PdMe2(tmeda) and PdXMe(tmeda) (X = Cl, Br, I), PdMe2(dppf) and PdXMe(dppf) (X = Cl, Br, I), cis-PdMe2(PPh3)2 and trans-PdClMe(PPh3)2 (X = Cl, Br, I), and trans-PdXMe(bpy) (X = Cl, Br, I).

Item Type: Article
Authors/Creators:Byers, PK and Canty, AJ and Jin, H and Kruis, D and Markies, BA and Boersma, J and van Koten, G and Hill, GS and Irwin, MJ and Rendina, LM and Puddephatt, RJ
Journal or Publication Title: Inorganic Syntheses
ISSN: 0073-8077
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restricted - published John Wiley & Sons, Inc Sherpa -"On personal web site only Published source must be acknowledged with set phrase Publisher's version/PDF cannot be used Articles in some journals can be made Open Access on payment of additional charge

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