Full text not available from this repository.

Abstract

This communication describes the synthesis of a series of diphosphine NiII(Ph)(CF3) complexes and studies of their reactivity toward oxidatively induced Ph–CF3 bond-forming reductive elimination. Treatment of these complexes with the one-electron outer-sphere oxidant ferrocenium hexafluorophosphate (FcPF6) affords benzotrifluoride, but the yield varies dramatically as a function of diphosphine ligand. Diphosphines with bite angles of less than 92° afforded 3. In contrast, those with bite angles between 95 and 102° formed PhCF3 in yields ranging from 62 to 77%.

Item Type:	Article
Authors/Creators:	Bour, JR and Roy, P and Canty, AJ and Kampf, JW and Sanford, MS
Keywords:	nickel (III), computation, DFT, carbon-carbon coupling
Journal or Publication Title:	Organometallics
Publisher:	Amer Chemical Soc
ISSN:	0276-7333
DOI / ID Number:	https://doi.org/10.1021/acs.organomet.9b00678
Copyright Information:	Copyright 2019 American Chemical Society
Related URLs:	UTAS Profile: Canty, AJ
Item Statistics:	View statistics for this item

Actions (login required)

Item Control Page