Open Access Repository

Suzuki-Miyaura Csp2-Csp2 cross-couplings employing nickel(II) pincer precatalysts: mechanistic investigations

Ho, CC ORCID: 0000-0002-7555-0635, Olding, A, Fuller, RO ORCID: 0000-0003-3926-8680, Canty, AJ, Lucas, NT and Bissember, AC ORCID: 0000-0001-5515-2878 2021 , 'Suzuki-Miyaura Csp2-Csp2 cross-couplings employing nickel(II) pincer precatalysts: mechanistic investigations' , Organometallics, vol. 40, no. 14 , pp. 2305-2310 , doi: 10.1021/acs.organomet.1c00033.

Full text not available from this repository.

Abstract

This study investigates the mechanism of Suzuki-Miyaura Csp2-Csp2 cross-couplings facilitated by PCP-type nickel(II) pincer complexes. By employing a combination of standard experimental and theoretical methods, it is proposed that a nickel(I)/(III) cycle is involved in this reaction and single-electron pathways likely operate in this transformation.

Item Type: Article
Authors/Creators:Ho, CC and Olding, A and Fuller, RO and Canty, AJ and Lucas, NT and Bissember, AC
Keywords: Suzuki-Miyaura, cross-coupling, nickel, mechanism
Journal or Publication Title: Organometallics
Publisher: Amer Chemical Soc
ISSN: 0276-7333
DOI / ID Number: 10.1021/acs.organomet.1c00033
Copyright Information:

© 2021 American Chemical Society

Related URLs:
Item Statistics: View statistics for this item

Actions (login required)

Item Control Page Item Control Page
TOP