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Ethylene Tri- and Tetramerization with Borate Cocatalysts: Effects on Activity, Selectivity, and Catalyst Degradation Pathways
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McGuinness, DS, Overett, M, Tooze, RP, Blann, K, Dixon, JT and Slawin, AMZ 2007
, 'Ethylene Tri- and Tetramerization with Borate Cocatalysts: Effects on Activity, Selectivity, and Catalyst Degradation Pathways'
, Organometallics, vol. 26, no. 4
, pp. 1108-1111
, doi: 10.1021/om060906z.
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Official URL: http://dx.doi.org/10.1021/om060906z
Abstract
In recent years the chromium-catalyzed oligomerization of
ethylene to linear R-olefins (LAOs) has been extensively studied
both in industry and in academia, due in part to increased
demand for LAOs, particularly the co-monomers 1-hexene and
1-octene. Recent work includes the development of increasingly
more active systems for full-range oligomerization,1 a variety
of Cr-based ethylene trimerization systems,2-4 and the first
example of selective ethylene tetramerization to 1-octene.5
Item Type: | Article |
---|---|
Authors/Creators: | McGuinness, DS and Overett, M and Tooze, RP and Blann, K and Dixon, JT and Slawin, AMZ |
Journal or Publication Title: | Organometallics |
Publisher: | American Chemical Society |
ISSN: | 0276-7333 |
DOI / ID Number: | 10.1021/om060906z |
Additional Information: | Copyright © 2007 American Chemical Society |
Item Statistics: | View statistics for this item |
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