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Ethylene Tri- and Tetramerization with Borate Cocatalysts: Effects on Activity, Selectivity, and Catalyst Degradation Pathways

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McGuinness, DS, Overett, M, Tooze, RP, Blann, K, Dixon, JT and Slawin, AMZ 2007 , 'Ethylene Tri- and Tetramerization with Borate Cocatalysts: Effects on Activity, Selectivity, and Catalyst Degradation Pathways' , Organometallics, vol. 26, No. 4 , pp. 1108-1111 , doi: 10.1021/om060906z.

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Official URL: http://dx.doi.org/10.1021/om060906z

Abstract

In recent years the chromium-catalyzed oligomerization of
ethylene to linear R-olefins (LAOs) has been extensively studied
both in industry and in academia, due in part to increased
demand for LAOs, particularly the co-monomers 1-hexene and
1-octene. Recent work includes the development of increasingly
more active systems for full-range oligomerization,1 a variety
of Cr-based ethylene trimerization systems,2-4 and the first
example of selective ethylene tetramerization to 1-octene.5

Item Type:	Article
Authors/Creators:	McGuinness, DS and Overett, M and Tooze, RP and Blann, K and Dixon, JT and Slawin, AMZ
Journal or Publication Title:	Organometallics
Publisher:	American Chemical Society
ISSN:	0276-7333
DOI / ID Number:	10.1021/om060906z
Additional Information:	Copyright © 2007 American Chemical Society
Item Statistics:	View statistics for this item

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