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Methyl 4-chloro-3,5-di-p-tolyl-1H-pyrrole-2-carboxylate dichloromethane hemisolvate


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Gardiner, MG, Jones, Roderick C, Ng, M and Smith, JA 2007 , 'Methyl 4-chloro-3,5-di-p-tolyl-1H-pyrrole-2-carboxylate dichloromethane hemisolvate' , Acta Crystallographica Section E, vol. 63, no. 1 , o197-0199 , doi: 10.1107/S1600536806052202.

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Recently, we have developed a synthetic procedure that allows
the controlled formation of mono- and diarylpyrroles by
chemoselective Suzuki–Miyaura coupling (Smith et al., 2006).
The key to the method was using chloride as a blocking group
which is not very reactive for cross-coupling, and then its
removal by catalytic hydrogenation.

Item Type: Article
Authors/Creators:Gardiner, MG and Jones, Roderick C and Ng, M and Smith, JA
Journal or Publication Title: Acta Crystallographica Section E
Publisher: Blackwell Publishing
ISSN: 1600-5368
DOI / ID Number: 10.1107/S1600536806052202
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