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Rhenium-catalysed reactions in chemical synthesis: selected case studies

Olding, A, Tang, M, Ho, CC ORCID: 0000-0002-7555-0635, Fuller, RO ORCID: 0000-0003-3926-8680 and Bissember, AC ORCID: 0000-0001-5515-2878 2022 , 'Rhenium-catalysed reactions in chemical synthesis: selected case studies' , Dalton Transactions, vol. 51, no. 8 , pp. 3004-3018 , doi: 10.1039/d1dt04205j.

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Abstract

This Perspective presents and discusses a selection of examples that reinforce the enabling and distinctive reactivity provided by homogeneous rhenium catalysis in chemical synthesis. Specifically, the ability for lower oxidation state rhenium-carbonyl catalysts to engage alkyne, allene, and enol substrates in various carbon-carbon bond-forming reactions is highlighted. The inherent capacity of Lewis acidic, higher oxidation state oxorhenium catalysts to facilitate the transposition/isomerisation of allyl alcohols and attendant functionalisation via reaction cascades is also showcased. A brief overview of representative rhenium catalysts that have allowed for reductions of imines, carbonyls, and related compounds is also provided.

Item Type: Article
Authors/Creators:Olding, A and Tang, M and Ho, CC and Fuller, RO and Bissember, AC
Keywords: rhenium, catalysis, chemical synthesis
Journal or Publication Title: Dalton Transactions
Publisher: Royal Soc Chemistry
ISSN: 1477-9226
DOI / ID Number: 10.1039/d1dt04205j
Copyright Information:

© The Royal Society of Chemistry 2022

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