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Rhenium-catalysed reactions in chemical synthesis: selected case studies



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Abstract
This Perspective presents and discusses a selection of examples that reinforce the enabling and distinctive reactivity provided by homogeneous rhenium catalysis in chemical synthesis. Specifically, the ability for lower oxidation state rhenium-carbonyl catalysts to engage alkyne, allene, and enol substrates in various carbon-carbon bond-forming reactions is highlighted. The inherent capacity of Lewis acidic, higher oxidation state oxorhenium catalysts to facilitate the transposition/isomerisation of allyl alcohols and attendant functionalisation via reaction cascades is also showcased. A brief overview of representative rhenium catalysts that have allowed for reductions of imines, carbonyls, and related compounds is also provided.
Item Type: | Article |
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Authors/Creators: | Olding, A and Tang, M and Ho, CC and Fuller, RO and Bissember, AC |
Keywords: | rhenium, catalysis, chemical synthesis |
Journal or Publication Title: | Dalton Transactions |
Publisher: | Royal Soc Chemistry |
ISSN: | 1477-9226 |
DOI / ID Number: | 10.1039/d1dt04205j |
Copyright Information: | © The Royal Society of Chemistry 2022 |
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Item Statistics: | View statistics for this item |
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