Full text not available from this repository.

Abstract

This Perspective presents and discusses a selection of examples that reinforce the enabling and distinctive reactivity provided by homogeneous rhenium catalysis in chemical synthesis. Specifically, the ability for lower oxidation state rhenium-carbonyl catalysts to engage alkyne, allene, and enol substrates in various carbon-carbon bond-forming reactions is highlighted. The inherent capacity of Lewis acidic, higher oxidation state oxorhenium catalysts to facilitate the transposition/isomerisation of allyl alcohols and attendant functionalisation via reaction cascades is also showcased. A brief overview of representative rhenium catalysts that have allowed for reductions of imines, carbonyls, and related compounds is also provided.

Item Type:	Article
Authors/Creators:	Olding, A and Tang, M and Ho, CC and Fuller, RO and Bissember, AC
Keywords:	rhenium, catalysis, chemical synthesis
Journal or Publication Title:	Dalton Transactions
Publisher:	Royal Soc Chemistry
ISSN:	1477-9226
DOI / ID Number:	10.1039/d1dt04205j
Copyright Information:	© The Royal Society of Chemistry 2022
Related URLs:	Google Scholar: Ho, CC UTAS Profile: Ho, CC UTAS Profile: Bissember, AC
Item Statistics:	View statistics for this item

Actions (login required)

Item Control Page