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Abstract

The use of micellar electrokinetic capillary chromatography (MEKC) for the separation of metal ions and metal-containing species is reviewed, together with the use of metal ions as a means to separate other species. Topics covered include the manipulation of separation selectivity through the use of complexation reactions induced by addition of a metal ion to the background electrolyte, enantiomeric separations facilitated through metal-analyte interactions, separation of organometallic species, separation of stable metal complexes in which the entire complex is the analyte and the separation of metal ions as analytes using pre-capillary or on-capillary complexation reactions with a suitable ligand.

Item Type:	Article
Authors/Creators:	Haddad, PR and Macka, M and Hilder, EF and Bogan, DP
Keywords:	Reviews; Background electrolyte composition; Enantiomer separation; Metal cations; Metal complexes; Organometallic compounds
Journal or Publication Title:	Journal of Chromatography A
ISSN:	0021-9673
DOI / ID Number:	https://doi.org/10.1016/S0021-9673(97)00373-7
Additional Information:	The definitive version is available at http://www.sciencedirect.com
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