Open Access Repository
Organopalladium and platinum chemistry in oxidising milieu as models for organic synthesis involving the higher oxidation states of palladium
Altmetric
Download Statistics
Downloads
Downloads per month over past year
Canty, AJ 2009
, 'Organopalladium and platinum chemistry in oxidising milieu as models for organic synthesis involving the higher oxidation states of palladium'
, Dalton Transactions, no. 47
, pp. 10409-10417
, doi: 10.1039/b914080h.
![]() |
PDF
Dalton_Persp_20...pdf | Request a copy Full text restricted Available under University of Tasmania Standard License. |
Official URL: http://dx.doi.org/10.1039/b914080h
Abstract
This perspective focuses on the higher oxidation state palladium(III) and palladium(IV)organometallic chemistry involving a range of strong oxidants, with consideration of platinum(III) and platinum(IV) chemistry where it is informative for the evaluation of structure and mechanism. Particular emphasis is placed on hypervalent iodine reagents, halogens and related oxidants of intense current interest in organic synthesis, together with linkages in concepts between this chemistry and recent advances in studies of diaryl disulfides, diaryl diselenides, and diaryl peroxides as oxidants. The chemistry of binuclear metal-metal bonded complexes of palladium and platinum is discussed.
Item Type: | Article |
---|---|
Authors/Creators: | Canty, AJ |
Keywords: | palladium(III), palladium(IV), platinum(III), platinum(IV), organopalladium, organoplatinum, organometallic mechanism, oxidative addition, reductive elimination, metal-metal bonds, binuclear complexes, homogeneous catalysis, palladium catalysis |
Journal or Publication Title: | Dalton Transactions |
ISSN: | 1477-9226 |
DOI / ID Number: | 10.1039/b914080h |
Item Statistics: | View statistics for this item |
Actions (login required)
![]() |
Item Control Page |